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Fully Automated Re-refining Plant


Toshi Group of Industries, Oil & Waste recycling facility meets or exceeds Federal and State Government Standards. It is licensed by Ministry of Petroleum & Chemicals(Deptt. of Petroleum & Natural Gas), Registered with Ministry of Environment & Forest, Govt of India and UP Pollution Control Board, Lucknow and Central Pollution Board.
Since 1978, We have committed ourselves to providing highest quality and affordable lubricating oils & greases to the industry using environment friendly technology to re-refine, package and distribute to our customer base. Our recycling plant was built in 1978 and uses state of the art laboratory, vacuum based re-refining, storage, packing and quality testing.

We continuously work hard to upgrade our plants quality, capacity and efficiency using innovative technologies and equipment imported from US and Germany. 
Our plant is located in Sikandrabad Industrial Area, Sikandrabad Dist. Bulandshar in the state of Uttar Pradesh (UP), 203205 India. It is about 40 Kilometers from New Delhi. Our plant is built on an area of 3073 square meter  consists of state of the art, world class equipment and technology monitored by highly skilled technicians and engineers.

 

Our Plant is fully automated and incorporates Several Sub-Systems, some of them are:

  • Power Generator
  • Used Oil Feed Storage
  • Waste Water Separator
  • Diesel Separator
  • Sludge/Metal/Asphalt Separator
  • Hydro-finishing
  • Fractional Distillation
  • Drum Cleaning & Re-conditioning
  • Settling & Storage Tanks/Containers
  • Water Based Recycled Cooling Towers
  • Testing and Research Laboratory

 

Licensed Incineration of Hazardous Waste

 

Toshi Group of Industries hazardous waste incinerator, consists of a rotary kiln (primary combustion chamber), an afterburner (secondary combustion chamber), connected to an air pollution control system, all of which are controlled and monitored.

Rotary kilns Both solid and liquid wastes are introduced into the rotary kiln, in which the temperature is typically above 1800°F.
Temperature is maintained at this level by using the heat content of the liquid wastes or by introducing supplemental fuels into the chamber, such as natural gas.
Liquid wastes generally are pumped into the kiln through nozzles, which atomize the liquids into fine droplets-as small as one microgram (one millionth of a gram)-for optimal combustion. Solid wastes may be fed into the kiln in bulk or in containers, using either a conveyer or a gravity feed system. The kiln slowly rotates so that the solid wastes are tumbled, to assure that they are exposed on all sides to the high temperature in the kiln, much as the rotation of a clothes dryer maximizes the exposure of the clothes to the hot air in the dryer. A large fan draws excess air (containing oxygen) into the system to increase combustion efficiency.

The flame and high temperature in the kiln cause the organic and some of the metal wastes to be converted from solids or liquids into hot gases. These hot gases pass into the afterburner. Any inorganic materials (metals, such as zinc or lead) that have not been converted into gases drop out as ash at the end of the kiln, into a container, for further management. (See "Residue Management," below).

Afterburner Atomized liquid wastes and/or supplemental fuel are injected into the afterburner, where temperatures are typically maintained at 2000°F. or higher. These atomized liquids and the hot gases entering the afterburner from the kiln are mixed with air and passed through the hot flame in the afterburner. The heat and flame break down the chemical bonds of the gaseous and atomized organic compounds into atoms. These atoms recombine with oxygen from the air in the chamber to form stable
compounds primarily composed of non-hazardous chemicals such as carbon dioxide and water (i.e., steam).

The gases exiting the secondary chamber are cooled and cleaned in the APCS. The APCS removes particulates (small solid matter) and the remaining hazardous constituents-such as metals which were not destroyed by the incineration process-down to levels established as safe by the regulations and the facility's permits. These levels are already more stringent than the risk standards established by the Clean Air Act of 1990 for future controls of emissions from manufacturing processes.

Controls and monitoring Operation within the key parameters of the combustion process are assured by systems of monitors and computer controls. These systems make automatic adjustments to key functions as necessary. For example, if temperatures begin to drop below desired levels, supplemental waste fuels are automatically injected. Conversely, if temperatures rise above the desired range, waste feeds are reduced.

All regulated incinerators have waste feed cut-offs (WFCOs) to assure protective operations. WFCOs automatically stop the feeding of waste into the incinerator if any of the key parameters even momentarily falls outside the narrow range of operating requirements.

There is also continuous monitoring and recording of key indicators, so that a permanent record is maintained, verifying operation of the incinerator within these parameters. Frequently, as many as twenty sCPCBrate parameters are monitored and recorded.

 
Residue management


The rotary kiln discharges an inorganic ash into a large container. The ash, and any residue from the APCS, is analyzed to assure that it does not contain any hazardous organic constituents above concentration levels specified in CPCB's regulations as safe for land disposal. These concentration levels are almost always less than one part per million for any organic hazardous constituent.

This inorganic residue is further treated by mixing it with chemical stabilizers to chemically bind the constituents. The chemically stabilized inorganic residue is analyzed to assure that the metals cannot leach out of the residue above the low levels specified in CPCB's rules. Finally, the stabilized and certified inorganic waste residue, which now meets all required treatment standards, is placed in a hazardous waste landfill meeting CPCB's Minimum Technology Requirements (MTR). MTR landfills have two liners, with a leachate collection system between the two liners. Groundwater monitoring is also provided, outside the landfill, to supplement the protection provided by the double-liner, leachate collection and leak detection systems of the MTR landfill itself.

Toshi Group of Industries's hazardous waste incinerators, operating under CPCB and UP state regulations, are high-technology devices, carefully designed, controlled and maintained to assure
(1) safe destruction of all hazardous organic constituents in the waste;
(2) control of emissions to safe levels, generally substantially below those met by manufacturing and other industries; and
(3) the proper treatment and safe disposal of any residues.

 
Destruction and Removal Efficiency (DRE)


Toshi Group of Industries incinerator burns a DRE of at least 99.999% ("five 9's").

A DRE of 99.99% means that 99.99% of the POHC's - the hazardous constituents in the waste -- have been destroyed by the incineration process or removed into the ash or the air pollution residues, for further treatment and disposal.

 
Waste Feed Cut-offs (WFCOs)


Toshi Group of Industries incinerator All hazardous waste incinerators must be operated with a system to cut off waste feeds automatically if key operating conditions deviate from the limits established in the permit. These include, as a minimum, carbon monoxide in the stack, combustion temperature and normally excess oxygen, combustion gas velocity, critical APCS control parameters, and others determined by the permitting agency to be necessary to ensure that the required performance standards are met.

 
Emissions


The incinerator is required, at a minimum, to limit emissions to not more than 4 pounds per hour of hydrogen chloride (HCl) and not more than 180 milligrams of particulate matter per cubic meter. Almost invariably, the permit will include other emission limits, such as for carbon monoxide and various metals, and may specify other, more stringent limits.

A risk analysis is conducted, based on the projected emissions of metals, HCl, etc., as demonstrated during the trial burn. The resultant risk must be significantly less than the future risk levels set by the Clean Air Act for manufacturing and other emission sources. In fact, if all stationary emission sources were held to standards similar to hazardous waste incinerators, there would not be an air pollution problem today.

 
SAFETY/ENVIRONMENTAL PROTECTION


Emissions from hazardous waste incinerators are the most tightly controlled and are the lowest of major manufacturing industries in the United States. For example, typical emission levels of hazardous waste incinerators are illustrated in a recent stack test of such an incinerator, in Ohio, overseen by the Ohio Environmental Protection Agency. The incinerator's annual emissions of particulates, as well as nitrogen oxide (Nox) and sulfur dioxide (SO2) - contributors to acid rain - compared to averages for other industrial facilities in the area, were:

Emission (Tons per year)

Type of Company
Particulates 
 NOx 
 SO2 
 Electric Power Plant
465
16,907
80,825
 Cement Kiln
370
632
2,896
 Steel Plant
310
1,643
42
 Automotive manufacturer
43
124
298
 Hazardous Waste Incinerator 
6
75
ND *
 College
6
32
504
 ND = Not Detected
 

Similarly, with respect to dioxins and furans, hazardous waste incinerators are typically operated at temperatures in excess of 2000° F, while maintaining excess oxygen on a regular basis. Under these conditions, dioxin and furans are not readily formed. These compounds have been detected at higher levels in other combustion devices (medical and garbage incinerators), which are operated at temperatures several hundred degrees lower than hazardous waste incinerators.

Source
Dioxin/Furan Emissions
(parts per billion)
 Home electrostatic precipitator
1.0
 Home fireplace soot
0.4
 Diesel truck muffler
0.023
 Automobile muffler
0.008
 Hazardous Waste Incinerator
0.0000015
 

Products of incomplete combustion (PICs) are sometimes formed in the incineration process as a result of non-combustion chemical reactions. Before being emitted, however, PICs that are formed in the incinerator are destroyed in the afterburner. After considerable study, CPCB has concluded that PIC emissions do not present any significant risk, provided that carbon monoxide is maintained at low levels. The required waste feed cutoff for carbon monoxide assures that this condition is continuously met.

With respect to total toxic emissions, CPCB recently reported that the estimated total emissions from all hazardous waste incinerators using "reasonable worst case assumptions" (emphasis added) – was less than 0.03% of the emissions of these same chemicals from manufacturing companies (as reported in the so-called "Toxic Release Inventory").

For example, the following table shows that total annual emissions of a typical hazardous waste incinerator, is far below comparable emissions from neighboring manufacturing plants.

Source
Toxic Release Inventory Emissions
(pounds per year)
 Chemical Plant
3,551,921
 Papermaking Plant
1,012,690
 Textile Plant
155,434
 Hazardous Waste Incinerator
156

Our industrial society produces large volumes of hazardous waste, and will continue to do so in the future, even with considerable efforts to minimize waste production. Furthermore, wastes presently not regulated, which pose substantial risks if not properly managed, will become regulated in coming years. Moreover, there are substantial volumes of existing hazardous wastes that must be cleaned up at Superfund and other contaminated sites.

A wide range of governmental, scientific, academic and environmental bodies and experts have concluded that modern, regulated, high temperature hazardous waste incinerators are safe, effective, controlled and monitored means of destroying organic hazardous and industrial wastes. They have also determined that it is clearly the best available technology in the country today for the destruction of organic wastes. In fact, if all air emission sources were as well designed, controlled, operated and regulated as hazardous waste incinerators, we would not have an air pollution problem in this country today.

Incineration is indeed the leading technology in India’s transition away from land disposal and toward permanent protection of public health and the environment. In this spirit of progress, the commercial incineration industry commits to working with local communities, the states and the Federal Government to not only information but to continuously advance incineration and make the best technology even better.


Rotary Kiln Incineration


A wide range of governmental, scientific, academic and environmental bodies and experts have concluded that modern, regulated, high temperature hazardous waste incinerators are safe, effective, controlled and monitored means of destroying organic hazardous and industrial wastes. They have also determined that it is clearly the best available technology in the country today for the destruction of organic wastes. In fact, if all air emission sources were as well designed, controlled, operated and regulated as hazardous waste incinerators, we would not have an air pollution problem in this country today.

Rotary kilns Both solid and liquid wastes are introduced into the rotary kiln, in which the temperature is typically above 1800°F.

Temperature is maintained at this level by using the heat content of the liquid wastes or by introducing supplemental fuels into the chamber, such as natural gas.
Liquid wastes generally are pumped into the kiln through nozzles, which atomize the liquids into fine droplets-as small as one microgram (one millionth of a gram)-for optimal combustion. Solid wastes may be fed into the kiln in bulk or in containers, using either a conveyer or a gravity feed system.

The kiln slowly rotates so that the solid wastes are tumbled, to assure that they are exposed on all sides to the high temperature in the kiln, much as the rotation of a clothes dryer maximizes the exposure of the clothes to the hot air in the dryer. A large fan draws excess air (containing oxygen) into the system to increase combustion efficiency.

The flame and high temperature in the kiln cause the organic and some of the metal wastes to be converted from solids or liquids into hot gases. These hot gases pass into the afterburner. Any inorganic materials (metals, such as zinc or lead) that have not been converted into gases drop out as ash at the end of the kiln, into a container, for further management. (See "Residue Management," below).

The rotary kiln discharges an inorganic ash into a large container. The ash, and any residue from the APCS, is analyzed to assure that it does not contain any hazardous organic constituents above concentration levels specified in CPCB's regulations as safe for land disposal. These concentration levels are almost always less than one part per million for any organic hazardous constituent.

This inorganic residue is further treated by mixing it with chemical stabilizers to chemically bind the constituents. The chemically stabilized inorganic residue is analyzed to assure that the metals cannot leach out of the residue above the low levels specified in CPCB's rules. Finally, the stabilized and certified inorganic waste residue, which now meets all required treatment standards, is placed in a hazardous waste landfill meeting CPCB's Minimum Technology Requirements (MTR). MTR landfills have two liners, with a leachate collection system between the two liners. Groundwater monitoring is also provided, outside the landfill, to supplement the protection provided by the double-liner, leachate collection and leak detection systems of the MTR landfill itself.


Laboratory Testing & Quality Assurance


Toshi Group of Industries has made considerable investments in setting up a test laboratory, equipped with measurement, heating, cooling and mini-process equipment to conduct a ‘live’ practical test scenario and test the sample for known hydrocarbons, metals, fuel, lube oil and gases. Our test laboratory is tightly integrated into the day to day business process. Every sample of product or residue produced from our process is tested starting from feed, fuel oil, water, distillate, asphalt, re-refined oil and to the final product. Every test conducted is logged on the computer in a database, where we maintain a comprehensive history of all feed sources, specs, process used along with parameters (Pressure, Temperature, Volume) and Catalyst used . The process parameters can be altered based on feed sample test results.

R&D at Toshi Group of Industries is based on a matrix organization, perfectly adapted to the multidisciplinary projects conducted by Toshi Group of Industries. Our research & development includes following active areas:

The entire process at Toshi Group of Industries is driven tightly with testing and compliance of specifications, also called TQM – Total Quality Management. Quality is relative and quantitative but better managed during and while manufacturing rather than simply testing the end-products. We have instituted a TQM process where at every step (or stage) the sample and catalysts are immediately tested on the spot using portable/mobile test equipment or in our lab (in many cases, prior to performing next stage). Toshi Group of Industries employees are fully trained on the quality process and are empowered to make decisions on the spot based on test results along with the Lab/QA Management. The Lab/QA reports directly to the R&D Director and/or Chief Operating Officer and serves as an independent & responsible unit ensuring consistent quality all the time to our customers.

In addition to measurement equipment, Toshi Group of Industries has setup small mini laboratory size plants to conduct tests prior to going live on the plant. We do that to ensure process parameters, quantitative analysis of catalyst/solvent addition, thorough/complete distillation in vacuum columns.

 
TQM Goals:


  • Consistent & Better Product Quality (ISI or ASTM Spec) i.e. none/minimal changes in final product in each cycle
  • Faster Product Delivery Time 
  • Safer Environmentally Friendly By-products
  • Simple to Learn and "Operate" 
  • Better Worker and Plant Safety

Research and Development


 

Research and Development (R&D) at Toshi Group of Industries is by vocation applied, covering most technical fields related to lube oil, their derivatives, processes, catalyst and substitutes: refining, hydro-cracking, hydro-treating, advanced instrumentation & control, operation optimization, environment protection, safety and the rational use of energy.

R&D at Toshi Group of Industries is based on a matrix organization, perfectly adapted to the multidisciplinary projects conducted by Toshi Group of Industries. Our research & development includes following active areas:

  » Advanced Fluid Catalytic Cracking
  » Economical Hydro-finishing of Lube Oils
  » Hazardous Waste Management & Re-use of Energy
  » Analysis & Safe Applications of Ash & Asphalt
  » Technologies or Re-refining Lube Oils (Liquid Propane/NMP/Butane, Meinken system modernized with thin film evaporators, furfural extraction or solvent extraction)
  » Optimized Management of eWaste & Biomedical Waste

Toshi Group of Industries actively conducts research in discovering newer ways to improve product extraction and quality with the following goals:

  » Equal or Better Product Quality (ISI or ASTM Spec)
  » Cheaper TCO (Total Cost of Ownership); Capital Cost as pertaining to Developing World, Cost of Maintenance, Replacement Cost/Availability of Parts and Skill set
  » Lower Operating Cost per Unit of the Product
  » Faster Product Delivery Time
  » Safer Environmentally Friendly By-products
  » Wider availability of raw material/catalysts/solvents or process resources
  » Simple to Learn and Operate
  » Better Worker and Plant Safety